A Highly Selective Vanadium Catalyst for Benzylic C-H Oxidation.
نویسندگان
چکیده
Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp(2)VCl(2) catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.
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ورودعنوان ژورنال:
- Chemical science
دوره 3 7 شماره
صفحات -
تاریخ انتشار 2012